Short Communication: Kinetics and Mechanism of Oxidation of Diallylamine by Alkaline Hexacyanoferrate (III)
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Article info
37 - 44
Keywords
Abstract
The kinetics of oxidation of diallylamine by hexacyanoferrate (III) in alkaline aqueous ethanol at constant ionic strength has been studied. The rate of the reaction was dependent on the first power of the concentration of diallylamine, but was independent of hexacyanoferrate (III) concentration. The rate was enhanced by an increase in the pH value The effects of added hexacyanoferrate (II), ionic strength, types of anion and cation, and the solvent composition have also been investigated. The activation parameters were evaluated. A mechanism consistent with the kinetic results is proposed and discussed.
Al-Subu, M. M. (1992). Short Communication: Kinetics and Mechanism of Oxidation of Diallylamine by Alkaline Hexacyanoferrate (III). An-Najah University Journal for Research - A (Natural Sciences), 7(1), 37–44. https://doi.org/10.35552/anujr.a.7.1.430
[1]M. M. Al-Subu, “Short Communication: Kinetics and Mechanism of Oxidation of Diallylamine by Alkaline Hexacyanoferrate (III),” An-Najah University Journal for Research - A (Natural Sciences), vol. 7, no. 1, pp. 37–44, Jan. 1992, doi: 10.35552/anujr.a.7.1.430.
Al-Subu, M. M. “Short Communication: Kinetics and Mechanism of Oxidation of Diallylamine by Alkaline Hexacyanoferrate (III).” An-Najah University Journal for Research - A (Natural Sciences), vol. 7, no. 1, Jan. 1992, pp. 37–44. Crossref, https://doi.org/10.35552/anujr.a.7.1.430.
1.Al-Subu MM. Short Communication: Kinetics and Mechanism of Oxidation of Diallylamine by Alkaline Hexacyanoferrate (III). An-Najah University Journal for Research - A (Natural Sciences) [Internet]. 1992 Jan;7(1):37–44. Available from: http://dx.doi.org/10.35552/anujr.a.7.1.430
Al-Subu, M. M. “Short Communication: Kinetics and Mechanism of Oxidation of Diallylamine by Alkaline Hexacyanoferrate (III).” An-Najah University Journal for Research - A (Natural Sciences) 7, no. 1 (January 1992): 37–44. https://doi.org/10.35552/anujr.a.7.1.430.
Short Communication: Kinetics and Mechanism of Oxidation of Diallylamine by Alkaline Hexacyanoferrate (III)
المؤلفون:
معلومات المقال
37 - 44
الكلمات الإفتتاحية
الملخص
The kinetics of oxidation of diallylamine by hexacyanoferrate (III) in alkaline aqueous ethanol at constant ionic strength has been studied. The rate of the reaction was dependent on the first power of the concentration of diallylamine, but was independent of hexacyanoferrate (III) concentration. The rate was enhanced by an increase in the pH value The effects of added hexacyanoferrate (II), ionic strength, types of anion and cation, and the solvent composition have also been investigated. The activation parameters were evaluated. A mechanism consistent with the kinetic results is proposed and discussed.
Al-Subu, M. M. (1992). Short Communication: Kinetics and Mechanism of Oxidation of Diallylamine by Alkaline Hexacyanoferrate (III). An-Najah University Journal for Research - A (Natural Sciences), 7(1), 37–44. https://doi.org/10.35552/anujr.a.7.1.430
[1]M. M. Al-Subu, “Short Communication: Kinetics and Mechanism of Oxidation of Diallylamine by Alkaline Hexacyanoferrate (III),” An-Najah University Journal for Research - A (Natural Sciences), vol. 7, no. 1, pp. 37–44, Jan. 1992, doi: 10.35552/anujr.a.7.1.430.
Al-Subu, M. M. “Short Communication: Kinetics and Mechanism of Oxidation of Diallylamine by Alkaline Hexacyanoferrate (III).” An-Najah University Journal for Research - A (Natural Sciences), vol. 7, no. 1, Jan. 1992, pp. 37–44. Crossref, https://doi.org/10.35552/anujr.a.7.1.430.
1.Al-Subu MM. Short Communication: Kinetics and Mechanism of Oxidation of Diallylamine by Alkaline Hexacyanoferrate (III). An-Najah University Journal for Research - A (Natural Sciences) [Internet]. 1992 Jan;7(1):37–44. Available from: http://dx.doi.org/10.35552/anujr.a.7.1.430
Al-Subu, M. M. “Short Communication: Kinetics and Mechanism of Oxidation of Diallylamine by Alkaline Hexacyanoferrate (III).” An-Najah University Journal for Research - A (Natural Sciences) 7, no. 1 (January 1992): 37–44. https://doi.org/10.35552/anujr.a.7.1.430.
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