Kinetic Study of the Complexation of Palladium (II) With 2-(5-Bromo-2-Pyridylazo)-5-Diethylaminophenol


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12 - 19

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Abstract

The kinetics of the complexation reaction of palladium with 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol (5-Br-PADAP) has been studied in the stability time at the optimum pH of 3.53 in presence of 50% ethanol. The effect of ionic strength and temperature on the reaction rate were reported. A mechanism has been postulated and the stability constants of the individual steps were determined. The Arrhenius and thermodynamic parameters were evaluated and discussed.

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Kinetic Study of the Complexation of Palladium (II) With 2-(5-Bromo-2-Pyridylazo)-5-Diethylaminophenol


معلومات المقال

12 - 19

الكلمات الإفتتاحية

الملخص

The kinetics of the complexation reaction of palladium with 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol (5-Br-PADAP) has been studied in the stability time at the optimum pH of 3.53 in presence of 50% ethanol. The effect of ionic strength and temperature on the reaction rate were reported. A mechanism has been postulated and the stability constants of the individual steps were determined. The Arrhenius and thermodynamic parameters were evaluated and discussed.

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