An-Najah University Journal for Research - A (Natural Sciences)

Adsorptive Cathodic Stripping Voltammetric Studies of Emodin

Article info

1998-09-22
1999-08-31
1999-08-31
57 - 66

Keywords

Abstract

A differential pulse cathodic stripping voltammetric (DP-CSV) method for determination of emodin in Britton- Robinson buffer (pH2) at a hanging mercury drop electrode (HMIDE) is described. The method is based on measuring the reductive peak height at —0.25V vs. Ag/AgCl reference electrode. The linear relationship between the peak current and emodin concentration allowed the voltarnmetric determination of emodin over a wide concentration range 1.0 X 10-2 —2.5 X10-6 M, with a relative standard deviation of 3.3% (10 determinations at 1 X 10-2 M). Adsorption of emodin at HMDE enabled a detection limit of 2X10-1°M after 3 min accumulation at 0.0V. The applicability of the suggested method was found to be suitable for the determination of emodin in roots, stems and leaves of Rumex cyprius plant.

Recommended Citation

Hannoun, M. A. (1999). Adsorptive Cathodic Stripping Voltammetric Studies of Emodin. An-Najah University Journal for Research - A (Natural Sciences), 13(1), 57–66. https://doi.org/10.35552/anujr.a.13.1.381
[1]M. A. Hannoun, “Adsorptive Cathodic Stripping Voltammetric Studies of Emodin,” An-Najah University Journal for Research - A (Natural Sciences), vol. 13, no. 1, pp. 57–66, Jan. 1999, doi: 10.35552/anujr.a.13.1.381.
Hannoun, Mohammad A. “Adsorptive Cathodic Stripping Voltammetric Studies of Emodin.” An-Najah University Journal for Research - A (Natural Sciences), vol. 13, no. 1, Jan. 1999, pp. 57–66. Crossref, https://doi.org/10.35552/anujr.a.13.1.381.
1.Hannoun MA. Adsorptive Cathodic Stripping Voltammetric Studies of Emodin. An-Najah University Journal for Research - A (Natural Sciences) [Internet]. 1999 Jan;13(1):57–66. Available from: http://dx.doi.org/10.35552/anujr.a.13.1.381
Hannoun, Mohammad A. “Adsorptive Cathodic Stripping Voltammetric Studies of Emodin.” An-Najah University Journal for Research - A (Natural Sciences) 13, no. 1 (January 1999): 57–66. https://doi.org/10.35552/anujr.a.13.1.381.

دراسات كهروكيماوية على مركب الايمودين بطريقة الانتزاع الكاثودي الامتصاصي
المؤلفون:

معلومات المقال

1998-09-22
1999-08-31
1999-08-31
57 - 66

الكلمات الإفتتاحية

الملخص

A differential pulse cathodic stripping voltammetric (DP-CSV) method for determination of emodin in Britton- Robinson buffer (pH2) at a hanging mercury drop electrode (HMIDE) is described. The method is based on measuring the reductive peak height at —0.25V vs. Ag/AgCl reference electrode. The linear relationship between the peak current and emodin concentration allowed the voltarnmetric determination of emodin over a wide concentration range 1.0 X 10-2 —2.5 X10-6 M, with a relative standard deviation of 3.3% (10 determinations at 1 X 10-2 M). Adsorption of emodin at HMDE enabled a detection limit of 2X10-1°M after 3 min accumulation at 0.0V. The applicability of the suggested method was found to be suitable for the determination of emodin in roots, stems and leaves of Rumex cyprius plant.

Recommended Citation

Hannoun, M. A. (1999). Adsorptive Cathodic Stripping Voltammetric Studies of Emodin. An-Najah University Journal for Research - A (Natural Sciences), 13(1), 57–66. https://doi.org/10.35552/anujr.a.13.1.381
[1]M. A. Hannoun, “Adsorptive Cathodic Stripping Voltammetric Studies of Emodin,” An-Najah University Journal for Research - A (Natural Sciences), vol. 13, no. 1, pp. 57–66, Jan. 1999, doi: 10.35552/anujr.a.13.1.381.
Hannoun, Mohammad A. “Adsorptive Cathodic Stripping Voltammetric Studies of Emodin.” An-Najah University Journal for Research - A (Natural Sciences), vol. 13, no. 1, Jan. 1999, pp. 57–66. Crossref, https://doi.org/10.35552/anujr.a.13.1.381.
1.Hannoun MA. Adsorptive Cathodic Stripping Voltammetric Studies of Emodin. An-Najah University Journal for Research - A (Natural Sciences) [Internet]. 1999 Jan;13(1):57–66. Available from: http://dx.doi.org/10.35552/anujr.a.13.1.381
Hannoun, Mohammad A. “Adsorptive Cathodic Stripping Voltammetric Studies of Emodin.” An-Najah University Journal for Research - A (Natural Sciences) 13, no. 1 (January 1999): 57–66. https://doi.org/10.35552/anujr.a.13.1.381.

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