Homogeneous Catalysis of O-Silylation Reactions Using Tris (Acetylacetonato) Cobalt (III)
Authors:
Article info
35 - 430
Keywords
Abstract
Tris (acetylacetonato) cobalt (III), (Co(acac)3), has been used to catalyze o-silylation reactions of R 3 Siff (R.z.Et,Et0) with R OH (Rt-Et, i-Pr, t-.Bu and C6Hj-). No reaction has been observed at room temperature, but the reaction is apparently enhanced when carried out at a higher temperature. The rate of the reaction varies with varying the concentration of the saline or the alcohol. Using different types of alcohols and silanes greatly affects the rate of the reaction. The rate of the reaction is affected by varying the concentration of the complex (Co(acaci6)).
S.Hilal, H. (1986). Homogeneous Catalysis of O-Silylation Reactions Using Tris (Acetylacetonato) Cobalt (III). An-Najah University Journal for Research - A (Natural Sciences), 3(1), 35–430. https://doi.org/10.35552/anujr.a.3.1.458
[1]H. S.Hilal, “Homogeneous Catalysis of O-Silylation Reactions Using Tris (Acetylacetonato) Cobalt (III),” An-Najah University Journal for Research - A (Natural Sciences), vol. 3, no. 1, pp. 35–430, Jan. 1986, doi: 10.35552/anujr.a.3.1.458.
S.Hilal, Hikmat. “Homogeneous Catalysis of O-Silylation Reactions Using Tris (Acetylacetonato) Cobalt (III).” An-Najah University Journal for Research - A (Natural Sciences), vol. 3, no. 1, Jan. 1986, pp. 35–430. Crossref, https://doi.org/10.35552/anujr.a.3.1.458.
1.S.Hilal H. Homogeneous Catalysis of O-Silylation Reactions Using Tris (Acetylacetonato) Cobalt (III). An-Najah University Journal for Research - A (Natural Sciences) [Internet]. 1986 Jan;3(1):35–430. Available from: http://dx.doi.org/10.35552/anujr.a.3.1.458
S.Hilal, Hikmat. “Homogeneous Catalysis of O-Silylation Reactions Using Tris (Acetylacetonato) Cobalt (III).” An-Najah University Journal for Research - A (Natural Sciences) 3, no. 1 (January 1986): 35–430. https://doi.org/10.35552/anujr.a.3.1.458.
Homogeneous Catalysis of O-Silylation Reactions Using Tris (Acetylacetonato) Cobalt (III)
المؤلفون:
معلومات المقال
35 - 430
الكلمات الإفتتاحية
الملخص
Tris (acetylacetonato) cobalt (III), (Co(acac)3), has been used to catalyze o-silylation reactions of R 3 Siff (R.z.Et,Et0) with R OH (Rt-Et, i-Pr, t-.Bu and C6Hj-). No reaction has been observed at room temperature, but the reaction is apparently enhanced when carried out at a higher temperature. The rate of the reaction varies with varying the concentration of the saline or the alcohol. Using different types of alcohols and silanes greatly affects the rate of the reaction. The rate of the reaction is affected by varying the concentration of the complex (Co(acaci6)).
S.Hilal, H. (1986). Homogeneous Catalysis of O-Silylation Reactions Using Tris (Acetylacetonato) Cobalt (III). An-Najah University Journal for Research - A (Natural Sciences), 3(1), 35–430. https://doi.org/10.35552/anujr.a.3.1.458
[1]H. S.Hilal, “Homogeneous Catalysis of O-Silylation Reactions Using Tris (Acetylacetonato) Cobalt (III),” An-Najah University Journal for Research - A (Natural Sciences), vol. 3, no. 1, pp. 35–430, Jan. 1986, doi: 10.35552/anujr.a.3.1.458.
S.Hilal, Hikmat. “Homogeneous Catalysis of O-Silylation Reactions Using Tris (Acetylacetonato) Cobalt (III).” An-Najah University Journal for Research - A (Natural Sciences), vol. 3, no. 1, Jan. 1986, pp. 35–430. Crossref, https://doi.org/10.35552/anujr.a.3.1.458.
1.S.Hilal H. Homogeneous Catalysis of O-Silylation Reactions Using Tris (Acetylacetonato) Cobalt (III). An-Najah University Journal for Research - A (Natural Sciences) [Internet]. 1986 Jan;3(1):35–430. Available from: http://dx.doi.org/10.35552/anujr.a.3.1.458
S.Hilal, Hikmat. “Homogeneous Catalysis of O-Silylation Reactions Using Tris (Acetylacetonato) Cobalt (III).” An-Najah University Journal for Research - A (Natural Sciences) 3, no. 1 (January 1986): 35–430. https://doi.org/10.35552/anujr.a.3.1.458.
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