An-Najah University Journal for Research - A (Natural Sciences)

Short Communication: The Mechanism of 1- Octene Isomerization and Hydrosilylation Reaction Catalysed by Ru3(CO)12

Article info

175 - 183

Keywords

Abstract

Isomerization and hydrosilylation reactions of terminal olefins have been reported under thermal and photochemical conditions using Ru3 (C0) 12, 1, and HRu3 (CO)!!, 2,11 '0 In a very recent work, we reported E LI that 1 catalyses both Isomerization and hydrosilylation reactions of 1-octene (eq. 1). It has been found that the isomerization reaction occurs via lower nuclearity catalytic species that result from fragmentation of the mother cluster 1. Evidence in favour of concurrent cluster catalysis was also reported. On the other hand, the hydrosilylation reaction occurred via cluster catalysis at first and after some-time fragment catalysis occurred.

Recommended Citation

Hilal, H. S., Jondi, W., & Khalaf, S. (1994). Short Communication: The Mechanism of 1- Octene Isomerization and Hydrosilylation Reaction Catalysed by Ru3(CO)12. An-Najah University Journal for Research - A (Natural Sciences), 8(1), 175–183. https://doi.org/10.35552/anujr.a.8.1.416
[1]H. S. Hilal, W. Jondi, and S. Khalaf, “Short Communication: The Mechanism of 1- Octene Isomerization and Hydrosilylation Reaction Catalysed by Ru3(CO)12,” An-Najah University Journal for Research - A (Natural Sciences), vol. 8, no. 1, pp. 175–183, Jan. 1994, doi: 10.35552/anujr.a.8.1.416.
Hilal, Hikmat S., et al. “Short Communication: The Mechanism of 1- Octene Isomerization and Hydrosilylation Reaction Catalysed by Ru3(CO)12.” An-Najah University Journal for Research - A (Natural Sciences), vol. 8, no. 1, Jan. 1994, pp. 175–83. Crossref, https://doi.org/10.35552/anujr.a.8.1.416.
1.Hilal HS, Jondi W, Khalaf S. Short Communication: The Mechanism of 1- Octene Isomerization and Hydrosilylation Reaction Catalysed by Ru3(CO)12. An-Najah University Journal for Research - A (Natural Sciences) [Internet]. 1994 Jan;8(1):175–83. Available from: http://dx.doi.org/10.35552/anujr.a.8.1.416
Hilal, Hikmat S., Waheed Jondi, and Shukri Khalaf. “Short Communication: The Mechanism of 1- Octene Isomerization and Hydrosilylation Reaction Catalysed by Ru3(CO)12.” An-Najah University Journal for Research - A (Natural Sciences) 8, no. 1 (January 1994): 175–83. https://doi.org/10.35552/anujr.a.8.1.416.

Short Communication: The Mechanism of 1- Octene Isomerization and Hydrosilylation Reaction Catalysed by Ru3(CO)12

معلومات المقال

175 - 183

الكلمات الإفتتاحية

الملخص

Isomerization and hydrosilylation reactions of terminal olefins have been reported under thermal and photochemical conditions using Ru3 (C0) 12, 1, and HRu3 (CO)!!, 2,11 '0 In a very recent work, we reported E LI that 1 catalyses both Isomerization and hydrosilylation reactions of 1-octene (eq. 1). It has been found that the isomerization reaction occurs via lower nuclearity catalytic species that result from fragmentation of the mother cluster 1. Evidence in favour of concurrent cluster catalysis was also reported. On the other hand, the hydrosilylation reaction occurred via cluster catalysis at first and after some-time fragment catalysis occurred.

Recommended Citation

Hilal, H. S., Jondi, W., & Khalaf, S. (1994). Short Communication: The Mechanism of 1- Octene Isomerization and Hydrosilylation Reaction Catalysed by Ru3(CO)12. An-Najah University Journal for Research - A (Natural Sciences), 8(1), 175–183. https://doi.org/10.35552/anujr.a.8.1.416
[1]H. S. Hilal, W. Jondi, and S. Khalaf, “Short Communication: The Mechanism of 1- Octene Isomerization and Hydrosilylation Reaction Catalysed by Ru3(CO)12,” An-Najah University Journal for Research - A (Natural Sciences), vol. 8, no. 1, pp. 175–183, Jan. 1994, doi: 10.35552/anujr.a.8.1.416.
Hilal, Hikmat S., et al. “Short Communication: The Mechanism of 1- Octene Isomerization and Hydrosilylation Reaction Catalysed by Ru3(CO)12.” An-Najah University Journal for Research - A (Natural Sciences), vol. 8, no. 1, Jan. 1994, pp. 175–83. Crossref, https://doi.org/10.35552/anujr.a.8.1.416.
1.Hilal HS, Jondi W, Khalaf S. Short Communication: The Mechanism of 1- Octene Isomerization and Hydrosilylation Reaction Catalysed by Ru3(CO)12. An-Najah University Journal for Research - A (Natural Sciences) [Internet]. 1994 Jan;8(1):175–83. Available from: http://dx.doi.org/10.35552/anujr.a.8.1.416
Hilal, Hikmat S., Waheed Jondi, and Shukri Khalaf. “Short Communication: The Mechanism of 1- Octene Isomerization and Hydrosilylation Reaction Catalysed by Ru3(CO)12.” An-Najah University Journal for Research - A (Natural Sciences) 8, no. 1 (January 1994): 175–83. https://doi.org/10.35552/anujr.a.8.1.416.

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